Clapeyron equation hamugeš-e Clapeyron Fr.: équation de Clapeyron An equation that relates the temperature and pressure dependence of phases in equilibrium with the heat interaction and volume change associated with a phase change: dP/dT = L/T ΔV, where dP/dT is the slope of the coexistence curve, L is the → latent heat, T is the temperature, and ΔV is the volume change of the phase transition. Named after Émile Clapeyron (1799-1864), a French engineer and physicist, one of the founders of → thermodynamics; → equation. |
Clausius-Clapeyron equation hamugeš-e Clausius-Clapeyron Fr.: équation de Clausius-Clapeyron An approximation of the → Clapeyron equation for liquid-vapor equilibrium that incorporates the → ideal gas law and states that the logarithm of vapor pressure is inversely proportional to temperature. |