An Etymological Dictionary of Astronomy and Astrophysics
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Of a system, the quantity whose decrease gives the maximum amount of external work which is performed when any physical or chemical process is carried out reversibly at constant temperature. It is defined by F = U - TS, where U is the → internal energy, T the → absolute temperature, and S the final → entropy.

After the German physicist and physician Hermann Ludwig Ferdinand von Helmholtz (1821-1894), who made important contributions to the thermodynamics of gaseous systems; → free; → energy.