An Etymological Dictionary of Astronomy and Astrophysics

An → O star whose spectrum displays strong
N III 4634-4640-4642 emission and strong He II 4686 emission.
The N III lines are always much stronger than C III 4647-4650-4651 when the latter are present. Historically, Of stars were considered to belong to the peculiar category, hence the f notation (see below). In his thesis work, Walborn (1971, ApJS 23, 257) removed them from that category and established them as the normal O-type → supergiants. He also used the notation ((f)), (f), and f to describe the progression from strong He II 4686 absorption, through weakened/absent, to emission, respectively, correlated with increasing N III emission strength, subsequently showing that it is a luminosity sequence – the first such for stars earlier than O9.

See also: The reason for the Of designation is that the letters Oa-Oe were used in the original Harvard classification to denote various types of → Wolf-Rayet and OB spectra. Therefore Of was the next available when Plaskett and Pearce (1931, Pub. Dominion Ap. Obs 5, 99) wished to distinguish O-type spectra with selective emission in N III 4634-4640-4642 and He II 4686 (“selective” because other lines from the same ions appear in absorption); → star.